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利用共沉淀法成功制备出绿色、高效、具有磁性的介孔Fe/Cu双金属非均相催化剂（Fe-Cu-400），通过X射线衍射仪（XRD）、比表面积测试仪（BET）、场发射扫描电镜（FESEM）及X射线能谱仪（EDS）等表征手段对催化剂的结构、形貌等进行分析，并用制备的Fe-Cu-400催化剂活化过一硫酸盐（PMS）降解四环素（TC），研究了不同反应条件对降解效果的影响.结果表明Fe-Cu-400/PMS体系具有较好的降解效果，随着PMS浓度和初始pH的提高，TC降解效率明显增加；无机阴离子（H ₂ PO ₄ ^- 、HCO ₃ ^- 、Cl ^- ）均对TC的降解有不同程度的促进作用，而NO ₃ ^- 对TC的降解则表现出较弱的抑制作用.Fe-Cu-400在循环使用5次后仍具有较好活化性能.通过自由基抑制实验和XPS测试分析了Fe-Cu-400/PMS体系的活化机制和分解产生的主要活性物种.通过LC-MS结合TOC分析，推测出TC经水解、脱甲基、脱羟基和脱氨基作用达到降解和矿化. A green, highly efficient, and porous copper-ferrite heterogeneous catalyst (Fe-Cu-400) with good magnetism was synthesized via a coprecipitation method. The catalysts were characterized using XRD, BET, FESEM, and EDS. The performance of Fe-Cu-400 as a catalyst was evaluated by activating peroxymonosulfate (PMS) for degradation of tetracycline (TC) in aqueous solution and investigating the influence of several water parameters. The Fe-Cu-400/PMS system showed a greater TC degradation ability, and the degradation rate of TC was enhanced with an increase in the PMS concentration and the initial pH of the coupled Fe-Cu-400/PMS system. Anions including H ₂ PO ₄ ^- , HCO ₃ ^- , and Cl ^- promoted TC degradation, whereas NO ₃ ^- showed a low inhibitory influence. In addition, Fe-Cu-400 exhibited excellent reusability towards activating PMS for TC degradation after five runs of tests. Possible mechanisms of the activation of PMS by Fe-Cu-400 and the main reactive species were proposed based on radical identification tests and XPS analysis. Furthermore, a potential degradation pathway was proposed that included hydrolysis and sequential removal of N -methyl, hydroxyl, and amine functional groups according to the results of LC-MS and TOC detections.